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Co3O4/ZnO Modified Acupuncture Needle:Preparation and Application in Detecting Glucose
Author NameAffiliationE-mail
YUAN Hong-Wen School of Chinese Medicine, Beijing Key Lab of TCM Collateral Disease Theory Research, Capital Medical University, Beijing 100069, China  
WANG Yu-Lu The First Affiliated Hospital of Baotou Medical College of Inner Mongolia University of Science and Technology, Baotou, Inner Mongolia 014010, China  
MA Chi State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing 102249, China  
GENG Jun-Long School of Chinese Medicine, Beijing Key Lab of TCM Collateral Disease Theory Research, Capital Medical University, Beijing 100069, China  
ZHANG Li-Qiang State Key Laboratory of Heavy Oil Processing, China University of Petroleum-Beijing, Beijing 102249, China  
CUI Hai School of Chinese Medicine, Beijing Key Lab of TCM Collateral Disease Theory Research, Capital Medical University, Beijing 100069, China drcuihai@163.com 
Abstract: A Co3O4/ZnO acicular nanorod arrays (ANRAs) decorated acupuncture needle has been fabricated,which demonstrates a good performance for detecting the glucose.Firstly,the precursor Co (CO3)0.5(OH)·0.11H2O ANRAs were fabricated on the acupuncture needle through hydrothermal method.Thereafter,they could be completely converted to the Co3O4 ANRAs through annealing at 500℃ for 3 h in the air,then ZnO quantum dots (QDs) were decorated on the surface of Co3O4 ANRAs through dipping technique.It is found that Co3O4/ZnO ANRAs decorated acupuncture needle exhibits a good current response to glucose (2 264.27 μA·L·mmol-1·cm-2),meanwhile owning a fast response time (<4 s) and a detection limit as low as 0.311 μmol·L-1(S/N=3).Moreover,this acupuncture needle exhibited a high selectivity for glucose in human serum,against ascorbic acid and uric acid.
Keywords: Co3O4  ZnO  acupuncture needle  glucose  sensor
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YUAN Hong-Wen,WANG Yu-Lu,MA Chi,GENG Jun-Long,ZHANG Li-Qiang,CUI Hai.Co3O4/ZnO Modified Acupuncture Needle:Preparation and Application in Detecting Glucose[J].Chinese Journal of Inorganic Chemistry,2017,33(7):1139-1146.
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Chinese Journal of Inorganic Chemistry