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| Syntheses, Structures and Biomimetic Catalytic Bromination of Copper-Triflusal Complexes |
| Author Name | Affiliation | E-mail | | WANG Ying | College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China | | | LIN Xiao-Meng | College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China | | | BAI Feng-Ying | College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China | baifengying2000@163.com | | ZHANG Rui | College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China | | | ZHANG Xiao-Xi | College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China | |
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| Abstract: A series of 2-hydroxy-4-trifluoromethylbenzoic acid(h2tba)-copper complexes:[Cu(htba)2(pz)2] (1),[Cu(htba)(2,2'-bipy)](htba) (2) and[Cu(htba)2(4,4'-bipy)] (3) (h2tba=2-hydroxy-4-trifluoromethylbenzoic acid, pz=pyrazole, 2,2'-bipy=2,2'-bipyridine, 4,4'-bipy=4,4'-bipyridine) have been synthesized and characterized by elemental analysis, IR spectra, UV-Vis, spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermal gravimetric analysis (TG). The complexes which catalyzed phenol red bromination in the presence of H2O2 and bromide, exhibited high catalytic bromination activity. |
| Keywords: copper complexes triflusal crystal structure catalytic bromination |
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| WANG Ying,LIN Xiao-Meng,BAI Feng-Ying,ZHANG Rui,ZHANG Xiao-Xi.Syntheses, Structures and Biomimetic Catalytic Bromination of Copper-Triflusal Complexes[J].Chinese Journal of Inorganic Chemistry,2017,33(9):1667-1677. |
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