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Recent Progress of Crystalline and Porous Polymer-Metal Coordination Complexes: Synthesis, Characterization and Properties |
Author Name | Affiliation | E-mail | YU Qi | College of Chemistry, Nankai University, Tianjin 300071, China | | CHEN Yao | State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, China College of Pharmacy, Nankai University, Tianjin 300071, China | | ZHANG Zhen-Jie | College of Chemistry, Nankai University, Tianjin 300071, China State Key Laboratory of Medicinal Chemical Biology, Nankai University, Tianjin 300071, China | zhangzhenjie@nankai.edu.cn | CHENG Peng | College of Chemistry, Nankai University, Tianjin 300071, China | pcheng@nankai.edu.cn |
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Abstract: It is always a great challenge to synthesize crystalline and porous polymer materials due to the random configuration and flexibility of polymers. However, polymer-metal coordination complexes (PMCCs) can exhibit high porosity and crystallinity because PMCCs possess not only the properties of polymers such as flexibility and good processability but also the properties of coordination complexes such as high crystallinity and porosity. Herein, this review article summarizes the methods how to construct porous and crystalline PMCCs including photo-induced polymerization method, coordination bond induced self-assembly method, two-step synthesis method and post-synthetic modification method. Finally, we discusse the characterization methods and the potential applications of PMCCs, and list the challenges and chances in the field. |
Keywords: crystallinity porosity polymer-metal coordination complexes post-synthetic modification self-assembly 0 Introduction |
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YU Qi,CHEN Yao,ZHANG Zhen-Jie,CHENG Peng.Recent Progress of Crystalline and Porous Polymer-Metal Coordination Complexes: Synthesis, Characterization and Properties[J].Chinese Journal of Inorganic Chemistry,2017,33(11):1991-2004. |
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