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| Platinum Nanoparticle-Decorated Porous Porphyrin-Based Metal-Organic Framework for Photocatalytic Hydrogen Production |
| Author Name | Affiliation | E-mail | | WANG Qiang | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
Fujian Normal University, Fuzhou, Fujian 350007, China | | | XU Rui | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China | | | WANG Xu-Sheng | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China | | | LIU Si-De | Fujian Normal University, Fuzhou, Fujian 350007, China | | | HUANG Yuan-Biao | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China | rcao@fjirsm.ac.cn | | CAO Rong | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China | ybhuang@fjirsm.ac.cn |
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| Abstract: Herein, Pt NPs of ca. 2.5 nm incorporated inside the mesopores of porphyrin-based MOF PCN-222, denoted as Pt@PCN-222, were prepared using double-solvent method followed by visible-light reduction. The obtained mesoporous MOF composite Pt@PCN-222 can effectively adsorb visible-light to promote the water splitting for hydrogen production, which gives a H2 yield of 253 μmol·g-1·h-1. |
| Keywords: metal-organic framework mesopore PCN-222 platinum nanoparticles water splitting for hydrogen production 0 Introduction |
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| WANG Qiang,XU Rui,WANG Xu-Sheng,LIU Si-De,HUANG Yuan-Biao,CAO Rong.Platinum Nanoparticle-Decorated Porous Porphyrin-Based Metal-Organic Framework for Photocatalytic Hydrogen Production[J].Chinese Journal of Inorganic Chemistry,2017,33(11):2038-2044. |
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