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Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2,6-di(pyrazin-2-yl)pyridine Ligand |
Author Name | Affiliation | E-mail | XIE Jia-Ze | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China | | WANG Da-Peng | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China | | MA Jian-Ping | School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China | | WANG Hai-Ying | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China | haiyingqd@163.com | ZUO Jing-Lin | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China | |
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Abstract: The tetrathiafulvalene (TTF) functionalized 2,6-di(pyrazin-2-yl)pyridine derivative, 4-tetrathiafulvalene-2,6-di(pyrazin-2-yl)pyridine (L), was designed and synthesized. Based on L, one electrochemically active TTF-containing Fe(Ⅱ) complex, namely, [Fe(Ⅱ)(L)2](BF4)2·2.75CH3CN·0.25CH2Cl2 (1), was synthesized and characterized by IR, elemental analysis, and X-ray single crystal diffraction. The complex 1 is formed by ligands and iron(Ⅱ) in a tridentate fashion. Complex 1 exhibits a discrete structure and features diverse nonclassical hydrogen bonding interactions, π…π and S…S interactions. In addition, magnetic, electrochemical, and spectroelectrochemistry properties for complex 1 have been studied. |
Keywords: tetrathiafulvalene Fe(Ⅱ) complex multifunctional materials crystal structure |
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XIE Jia-Ze,WANG Da-Peng,MA Jian-Ping,WANG Hai-Ying,ZUO Jing-Lin.Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2,6-di(pyrazin-2-yl)pyridine Ligand[J].Chinese Journal of Inorganic Chemistry,2017,33(11):2045-2050. |
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