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Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2,6-di(pyrazin-2-yl)pyridine Ligand
Author NameAffiliationE-mail
XIE Jia-Ze State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China  
WANG Da-Peng State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China  
MA Jian-Ping School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China  
WANG Hai-Ying State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China 
haiyingqd@163.com 
ZUO Jing-Lin State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China  
Abstract: The tetrathiafulvalene (TTF) functionalized 2,6-di(pyrazin-2-yl)pyridine derivative, 4-tetrathiafulvalene-2,6-di(pyrazin-2-yl)pyridine (L), was designed and synthesized. Based on L, one electrochemically active TTF-containing Fe(Ⅱ) complex, namely, [Fe(Ⅱ)(L)2](BF4)2·2.75CH3CN·0.25CH2Cl2 (1), was synthesized and characterized by IR, elemental analysis, and X-ray single crystal diffraction. The complex 1 is formed by ligands and iron(Ⅱ) in a tridentate fashion. Complex 1 exhibits a discrete structure and features diverse nonclassical hydrogen bonding interactions, π…π and S…S interactions. In addition, magnetic, electrochemical, and spectroelectrochemistry properties for complex 1 have been studied.
Keywords: tetrathiafulvalene  Fe(Ⅱ) complex  multifunctional materials  crystal structure
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XIE Jia-Ze,WANG Da-Peng,MA Jian-Ping,WANG Hai-Ying,ZUO Jing-Lin.Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2,6-di(pyrazin-2-yl)pyridine Ligand[J].Chinese Journal of Inorganic Chemistry,2017,33(11):2045-2050.
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Chinese Journal of Inorganic Chemistry