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Fabrication and Photocatalytic Properties of Hollow Sphere Cu2O with Different Surface Morphology |
Author Name | Affiliation | E-mail | YAO Xun | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | LI Ming-Gao | CRRC Institute Co., Ltd., Beijng 100070, China | lmg0520@126.com | XIE Yan-Chun | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | LIU Fei | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | LIU Qin | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | LIU Yang | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | LI Peng | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | XUE Rui-Ting | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | | FAN Xi-Mei | Key Laboratory of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China | fanximei@126.com |
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Abstract: The shape-controlled hollow sphere Cu2O nanomaterials were prepared by one-step solvothermal method, and used Cu(NO3)2·3H2O as raw material, ethylene glycol as reductant and polyvinylpyrrolidone (PVP) as surfactant. In this study, the influence of different mass ratios of Cu(NO3)2·3H2O and PVP (wCu(NO3)2·3H2O/wPVP) and reaction time on the crystal structures, morphologies, surface area and optical properties of Cu2O was researched. The photocatalytic mechanism of Cu2O nanocrystals are also investigated. The results show that the photocatalytic activity of Cu2O hollow spheres covered by nano-thorns is best when wCu(NO3)2·3H2O/wPVP=45, and at the 1 h of irradiation, the photodegradation efficiency of methyl orange solution can reach up to 94.3%. |
Keywords: shape-controlled hollow sphere Cu2O nanomaterials photocatalytic property |
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YAO Xun,LI Ming-Gao,XIE Yan-Chun,LIU Fei,LIU Qin,LIU Yang,LI Peng,XUE Rui-Ting,FAN Xi-Mei.Fabrication and Photocatalytic Properties of Hollow Sphere Cu2O with Different Surface Morphology[J].Chinese Journal of Inorganic Chemistry,2018,34(6):1086-1094. |
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