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| Structures and Properties of One Mixed-Ligand and Two Homoligand Coordination Polymers Based on 4-(Imidazol-1-yl)-benzoic Acid |
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| Abstract: Reactions of Cu(II) or Cd(II) salts, 4-(imidazol-1-yl)-benzoic acid (HIBA) with or without 5-nitroiso-phthalic acid (H2NPA) as co-ligand result in three coordination polymers (CPs), namely, {[Cu(IBA)2]·DMF}n (1), {[Cd(IBA)2(H2O)]·3H2O}n (2), and[Cd3(IBA)2(NPA)2]n (3). Compounds 1 and 2 exhibit 3D 4-and 3-fold interpene-trating diamondoid frameworks, respectively. Compound 3 displays a 3D mixed-ligand framework with 1D Cd-carboxylate secondary building blocks bridged by IBA- and NPA2- ligands. The phase purity and luminescent properties of selected compounds have also been explored. |
| Keywords: 4-(imidazol-1-yl)-benzoic acid coordination polymer crystal structure solid-state luminescent |
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| LI Tian-Tian,ZHENG Sheng-Run.Structures and Properties of One Mixed-Ligand and Two Homoligand Coordination Polymers Based on 4-(Imidazol-1-yl)-benzoic Acid[J].Chinese Journal of Inorganic Chemistry,2018,34(8):1566-1572. |
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