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Synthesis, Growth Mechanism and Application in Anticancer of CuS Hollow Spheres
Author NameAffiliationE-mail
HUANG Qing-Li Research Facility Center for Morphology of Xuzhou Medical University, Xuzhou, Jiangsu 221004, China qlhuang@yzu.edu.cn,qlhuang@xzhmu.edu.cn 
WANG Li-Li Research Facility Center for Morphology of Xuzhou Medical University, Xuzhou, Jiangsu 221004, China  
LI Ting Research Facility Center for Morphology of Xuzhou Medical University, Xuzhou, Jiangsu 221004, China  
WU Yong-Ping Research Facility Center for Morphology of Xuzhou Medical University, Xuzhou, Jiangsu 221004, China  
Abstract: Cage-like hollow morphologies of copper sulfide nanostructures have been selectively synthesized using cupric nitrate trihydrate (Cu(NO3)2·3H2O), oxalic acid (H2C2O4) and sodium sulphide nonahydrate (Na2S·9H2O) as starting materials in water solution by a self sacrificing templates hydrothermal method. X-ray diffraction (XRD), field scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM) were used to characterize the products. The possible formation mechanism of CuS hollow spheres was proposed. The photo-thermal conversion experiments were also done. The results showed that hollow CuS exhibited high photo-thermal efficiency and high anticancer activity under NIR irradiation.
Keywords: hydrothermal synthesis  crystal growth  radicals  reaction mechanisms
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HUANG Qing-Li,WANG Li-Li,LI Ting,WU Yong-Ping.Synthesis, Growth Mechanism and Application in Anticancer of CuS Hollow Spheres[J].Chinese Journal of Inorganic Chemistry,2019,35(2):314-322.
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Chinese Journal of Inorganic Chemistry