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| X-ray Crystallography, Spectral Characterization and Computational Studies of Mercury(Ⅱ) Complex with 1-(p-Tolyl)-2-(tri-p-tolyl-λ5-phosphanylidene)ethan-1-one |
| Author Name | Affiliation | E-mail | | Mahsa Pourmirza | Department of Chemistry, Faculty of Science, Urmia University, P O Box 57153-165, Urmia, Iran | | | Shahla Ebrahimnezhad | Department of Chemistry, Faculty of Science, Urmia University, P O Box 57153-165, Urmia, Iran | | | Ali Ramazani | Department of Chemistry, Faculty of Science, Zanjan University, P O Box 45195-313, Zanjan, Iran | | | Aidin Bahrami | Department of Chemistry, Faculty of Science, Urmia University, P O Box 57153-165, Urmia, Iran | | | Sholeh. Alaei | Department of physics, Faculty of Science, Urmia branch, Islamic Azad University, Urmia, Iran | | | Ali. Reza Dadrass | Department of Chemistry, Faculty of Science, Urmia University, P O Box 57153-165, Urmia, Iran | dadrassi@yahoo.com |
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| Abstract: The α-phosphorus ligand 1-(p-tolyl)-2-(tri-p-tolyl-λ5-phosphanylidene)ethan-1-one(L) was prepared by the reaction of 2-bromo-1-(p-tolyl)ethan-1-one with tri(p-tolyl) phosphine. The reactions of L with cadmium chloride and mercury bromide resulted in[Cd(L)Cl2]2 (C1) and[Hg(L)(μ2-Br)Br]2 (C2), respectively. The complexes were characterized by IR and NMR (1H, 13C, 31P). The structure of C2 was detected by single crystal X-ray diffraction and its DFT computational studies at B3LYP/6-31G* level were also performed to reveal the interaction between the reaction site of complex C2 and nucleophilic groups such as Schiff base. |
| Keywords: phosphorus ligand mercury(Ⅱ) halide complex tri(p-tolyl) phosphine |
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| Mahsa Pourmirza,Shahla Ebrahimnezhad,Ali Ramazani,Aidin Bahrami,Sholeh. Alaei,Ali. Reza Dadrass.X-ray Crystallography, Spectral Characterization and Computational Studies of Mercury(Ⅱ) Complex with 1-(p-Tolyl)-2-(tri-p-tolyl-λ5-phosphanylidene)ethan-1-one[J].Chinese Journal of Inorganic Chemistry,2019,35(2):344-350. |
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