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| Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers |
| Author Name | Affiliation | E-mail | | LIU Lu | School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China | liululiulu2012@126.com | | JIN Ping-Ning | Xinxiang Medical University, Xinxiang, Henan 453000, China | | | LI Ying | School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China | | | LOU Hui-Hui | School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China | | | WANG Jian-Ji | School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China | Jwang@henannu.edu.cn | | ZHANG Yu-Ping | School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China | | | HOU Hong-Wei | College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, China | | | DU Jin-Ge | Department of Chemistry, Sanquan College of Xinxiang Medical University, Xinxiang, Henan 453003, China | |
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| Abstract: Five coordination complexes, formulated as {[Zn(btbb)0.5(m-phda)]·0.5H2O}n (1), {[Cd2(btbb)(adtda)2(H2O)]·H2O}n (2),[Mn2(btbb)(tbi)2]n (3), {[Cd(btbb)0.5(3-Nitro-o-bdc)(H2O)]·H2O}n (4) and[Cd2(btbb)(tbi)2]n (5) (btbb=1,4-bis(2-(4-thiazolyl)benzimidazole-1-ylmethyl)benzene, m-H2phda=m-phenylenediacetic acid, H2adtda=1,3-adaman-tanedicarboxylic acid, H2tbi=5-tert-butylisophthalic acid, 3-Nitro-o-H2bdc=3-Nitro-1,2-benzenedicarboxylic acid), have been obtained by hydro(solv)thermal reactions and structurally characterized. Complex 1 exhibits a 1D chain structure containing 22-membered rings. Complex 2 features a 1D chain structure having an 8-membered rings and btbb serves only as an ornament here. Complex 3 is a 1D double chain structure. Complex 4 possesses a 1D chain structure containing 14-membered rings. Complex 5 shows a 1D double chain taking on stair-step. |
| Keywords: complex semi-rigid ligand carboxylate crystal structure |
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| LIU Lu,JIN Ping-Ning,LI Ying,LOU Hui-Hui,WANG Jian-Ji,ZHANG Yu-Ping,HOU Hong-Wei,DU Jin-Ge.Syntheses, Characterization and Crystal Structures of Five 1D Complexes Based on Semi-rigid Bis(thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers[J].Chinese Journal of Inorganic Chemistry,2019,35(6):1076-1084. |
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