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Layered Co3O4/Ti Nanosheet Flexible Electrode with Low Transfer Resistance for Supercapacitor
Author NameAffiliationE-mail
HAN Dan-Dan College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China luckhan2006@163.com 
ZHAO Yuan College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China  
SHEN Ye College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China  
DING Yuan-Sheng College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China  
CHENG Zhen-Yu College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin, Jilin 132022, China  
JING Xiao-Yan College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China  
ZHANG Xue-Yi Jilin Hospital of Integrated Traditional Chinese and Western Medicine, Jilin, Jilin 132012, China  
Abstract: The layered Co3O4 nanosheets with porous nature on Ti mesh were adopted to optimize the transfer resistance by a facile hydrothermal method. The synthesized materials were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical techniques. The results showed that the materials consisted of well-arranged micrometer length rectangular 2D flakes with uniform pore distribution. This unique microstructure obtained the electrode lower transfer resistance, higher structure stability, and better electrochemical performance for supercapacitor. The 2D porous layered Co3O4 nanosheet could achieve a relatively good capacitance retention of 91.8% at a current density of 100 mA·g-1 after 1 000 cycles and a low transfer resistance (Rct) of 0.29 Ω. These remarkable supercapacitive performances are attributed to the rationally 2D layered structure on flexible Ti mesh substrate, high utilization ratio of active materials of the flexible Co3O4/Ti electrode.
Keywords: flexible electrode  layered Co3O4  porous nanosheets  transfer resistance  supercapacior
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HAN Dan-Dan,ZHAO Yuan,SHEN Ye,DING Yuan-Sheng,CHENG Zhen-Yu,JING Xiao-Yan,ZHANG Xue-Yi.Layered Co3O4/Ti Nanosheet Flexible Electrode with Low Transfer Resistance for Supercapacitor[J].Chinese Journal of Inorganic Chemistry,2019,35(8):1485-1492.
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Chinese Journal of Inorganic Chemistry