Chinese Version
Home | About Journal | Editorial Board | Information for Authors | Copyright Transfer Statement | Contact us
Mesoporous SBA-15 Rods Supported Pd3Cl Catalysts for Sonogashira C-C Coupling
Author NameAffiliationE-mail
HE Rong Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		 
YUN Ya-Pei Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		 
SUN Li-Li Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		 
SHENG Hong-Ting Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		 
DU Yuan-Xin Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		 
XIANG Dong Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China  
LI Peng Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		peng-li@ahu.edu.cn 
YUAN Xiao-You Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China  
ZHU Man-Zhou Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China
Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University), Ministry of Education, Hefei 230601, China 		zmz@ahu.edu.cn 
HONG Xun Center of Advanced Nanocatalysis(CAN) and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China  
WU Yu-En Center of Advanced Nanocatalysis(CAN) and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China  
Abstract: In this work, atomically precise[Pd3Cl(PPh2)2(PPh3)3]+ (denoted as Pd3Cl) nanoclusters with high monodispersity were supported on the rod-like mesoporous SBA-15 by electrostatic attraction strategy. The well-defined Pd3Cl/SBA-15 catalysts exhibited good catalytic performance and recyclability for Sonogashira C-C coupling reaction under mild condition with environment-friendly water as solvent. Importantly, we investigated the relationship between structures and properties of Pd3Cl, which demonstrated that the synergistic effect between Pdδ+ (0 < δ < 2) and the ligand was the key to the catalytic reaction.
Keywords: atomically precise nanoclusters  SBA-15  electrostatic attraction  Sonogashira C-C coupling
Hits:  1232
Download times:  571
HE Rong,YUN Ya-Pei,SUN Li-Li,SHENG Hong-Ting,DU Yuan-Xin,XIANG Dong,LI Peng,YUAN Xiao-You,ZHU Man-Zhou,HONG Xun,WU Yu-En.Mesoporous SBA-15 Rods Supported Pd3Cl Catalysts for Sonogashira C-C Coupling[J].Chinese Journal of Inorganic Chemistry,2020,36(1):53-61.
View Full Text  View/Add Comment  Download reader
Chinese Journal of Inorganic Chemistry