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| Two 3D Pillar-Layered Homochiral Coordination Complexes: Syntheses, Structures and Properties |
| Author Name | Affiliation | E-mail | | XU Zhong-Xuan | School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China | xuzhongxuan4201@163.com | | BAI Xue-Lei | School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China | | | MENG Qin | School of Chemistry and Chemical Engineering, Zunyi Normal College, Zunyi, Guizhou 563002, China | |
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| Abstract: Two homochiral coordination polymers[Cd3((R)-CIA)2(bipy)2.5(H2O)2]·xGuest (1) and[Zn3((R)-CIA)(bmib)2(H2O)2Cl]·H2O·xGuest (2) ((R)-H3CIA=(R)-5-(1-carboxyethoxy) isophthalic acid, bipy=4,4'-bipyridine, bmib=1,4-bis(2-methyl-1H-imidazol-1-yl)benzene) were obtained under solvothermal reaction conditions. X-ray single crystal structure analysis reveals that complexes 1 and 2 are all 3D pillar-layered frameworks. From the viewpoint of structural topology, complex 1 possesses a (3,3,3,6,6)-connected net with a point symbol of (4.52)2(4.82)2(42.68.83. 102)(42.68.83.92)(5.8.9)2, while complex 2 is a (3,4,4)-connected net with a point symbol of (6·72)2(6·75)2(62·74). Moreover, thermal stabilities, CD spectra and luminescent properties of these new complexes have been studied. |
| Keywords: homochiral lactic acid derivative pillar-layered framework topology |
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| XU Zhong-Xuan,BAI Xue-Lei,MENG Qin.Two 3D Pillar-Layered Homochiral Coordination Complexes: Syntheses, Structures and Properties[J].Chinese Journal of Inorganic Chemistry,2020,36(1):165-172. |
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