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| Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties |
| Author Name | Affiliation | E-mail | | ZHAI Li-Jun | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China | | | ZHANG Jie | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China | | | GAO Ling-Ling | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China | | | GAO Ting | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China | | | JIA Jiao-Jiao | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China | | | NIU Yu-Lan | 1 Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China | niuyulan@163.com | | HU Tuo-Ping | Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China | hutuoping@nuc.edu.cn |
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| Abstract: Two new coordination polymers (CPs) based on H4tptc, namely, {[Zn2(tptc)(1,4-bimb)2]·H2O}n (1) and {[Ni(tptc)0.5(1,2-bimb)(H2O)]·H2O}n (2) (H4tptc=p-terphenyl-3,3",5,5"-tetracarboxylic acid, 1,4-bimb=1,4-bis (imid-azol-1-ylmethyl) benzene, 1,2-bimb=1,2-bis (imidazol-1-ylmethyl) benzene), have been synthesized under solvo-thermal conditions. The structural analyses reveal that complex 1 shows a 3D structure with the symbol of (86), while complex 2 presents a 2D layer network, which is further expanded into a 3D supramolecular structure through H-bonding interactions. Furthermore, the luminescence sensing of 1 for cations, anions as well as magnetic property of 2 have also been studied. |
| Keywords: aromatic tetracarboxylic acid coordination polymers luminescent properties magnetic properties |
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| ZHAI Li-Jun,ZHANG Jie,GAO Ling-Ling,GAO Ting,JIA Jiao-Jiao,NIU Yu-Lan,HU Tuo-Ping.Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties[J].Chinese Journal of Inorganic Chemistry,2020,36(1):173-182. |
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