Chinese Version
Home | About Journal | Editorial Board | Information for Authors | Copyright Transfer Statement | Contact us
Pentanuclear Sn(Ⅱ) Guanidinate Complex: Synthesis, Structure, and Catalytic Activity for Addition of Arylamines into N,N'-Diisopropylcarbodiimide
Author NameAffiliationE-mail
WANG Ying-Ying Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China  
TONG Hong-Bo Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China  
ZHOU Mei-Su Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China mszhou@sxu.edu.cn 
Abstract: A pentanuclear Sn(Ⅱ) guanidinate complex[PhNC(NMe)2N(H)SnCl]2[PhNC(NMe)2NSnCl]2Sn (1) was synthesized via the reaction of PhN(Li)SiMe3 and anhydrous tin(Ⅱ) chloride. It was well structurally characterized by 1H NMR, 13C NMR, elemental analysis, and X-ray single crystal crystallography techniques. Complex 1 is an active catalyst in the addition reaction of arylamines into N,N'-diisopropylcarbodiimide giving guanidinates. CCDC:1954650.
Keywords: tin(Ⅱ)  guanidinate  structure  catalytic addition
Hits:  919
Download times:  479
WANG Ying-Ying,TONG Hong-Bo,ZHOU Mei-Su.Pentanuclear Sn(Ⅱ) Guanidinate Complex: Synthesis, Structure, and Catalytic Activity for Addition of Arylamines into N,N'-Diisopropylcarbodiimide[J].Chinese Journal of Inorganic Chemistry,2020,36(8):1567-1572.
View Full Text  View/Add Comment  Download reader
Chinese Journal of Inorganic Chemistry