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Growth Process, Photoluminescence Property and Photocatalytic Activity of SnO2 Nanorods
Author NameAffiliationE-mail
ZHAN Hong-Quan School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China zhq_0425@163.com 
DENG Ce School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China  
LIU Quan School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China  
LI Xiao-Hong School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, Jiangxi 333403, China  
XIE Zhi-Peng School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China  
WANG Chang-An School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China  
Abstract: In this work, under the regulation of citric acid, SnO2 nanorods were synthesized by hydrothermal method. The structural characteristics of SnO 2 samples during the growth process was investigated by using high-resolution transmission electron microscope, X-ray diffraction, infrared spectra Fourier transform spectra, Brunauer-EmmettTeller nitrogen physisorption, UV-visible diffuse reflection spectrum, and photoluminescence spectra. The results reveal that the overall crystal growth can further be divided into two stages:the oriented attachment of SnO2 nanocrystals at the early stage and subsequently a slow crystal growth along the[001] direction following the Ostwald ripening mode. Photoluminescence property and photocatalytic activity of SnO2 nanoparticles at the different stages was also investigated, which show a similar changing trend with the crystal growing:greatly increased at the former stage and gradually decreased at the latter stage.
Keywords: SnO2  oriented attachment  Ostwald ripening  photocatalytic activity  photoluminescence
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ZHAN Hong-Quan,DENG Ce,LIU Quan,LI Xiao-Hong,XIE Zhi-Peng,WANG Chang-An.Growth Process, Photoluminescence Property and Photocatalytic Activity of SnO2 Nanorods[J].Chinese Journal of Inorganic Chemistry,2020,36(8):1605-1612.
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Chinese Journal of Inorganic Chemistry