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Surface Plasmon-Enhanced Upconversion Luminescence Properties of Silver Nano-rices
Author NameAffiliationE-mail
YANG Yang Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo, Zhejiang 315211, China  
WANG Yue Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, School of Physics&Materials Engineering, Dalian Minzu University, Dalian, Liaoning 116600, China  
CONG Yan Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, School of Physics&Materials Engineering, Dalian Minzu University, Dalian, Liaoning 116600, China congyan@dlnu.edu.cn 
CHEN Yong-Qi Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, School of Physics&Materials Engineering, Dalian Minzu University, Dalian, Liaoning 116600, China  
HUANG Yun-Chong Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, School of Physics&Materials Engineering, Dalian Minzu University, Dalian, Liaoning 116600, China  
Abstract: Upconversion nanoparticles have been limited to further development in the field of application due to their low luminescence efficiency. Surface plasmon modulation using noble metal has been developed as an effective way to enhance upconversion luminescence. In this work, the noble metal ricelike structure with a simple synthetic procedure was obtained through regulating the localized electric field around upconversion nanoparticles for improving upconversion luminescence intensity. The 3D finite element method was employed to investigate the effect of the different contact modes between Ag rices in the actual films on induced localized electric field enhancement. Further, this enhancement effect caused by plasmon-coupling is a crucial contribution in this upconversionmodulated system. And the upconversion intensity improvement of nearly 100 times was acquired. Finally, the upconversion luminescence performance can be further optimized by adjusting the thickness of the plasmonic layer and luminescence layer.
Keywords: Ag nano-rices  NaYF4:Yb3+, Tm3+  plasmon resonance effect
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YANG Yang,WANG Yue,CONG Yan,CHEN Yong-Qi,HUANG Yun-Chong.Surface Plasmon-Enhanced Upconversion Luminescence Properties of Silver Nano-rices[J].Chinese Journal of Inorganic Chemistry,2022,38(5):829-835.
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Chinese Journal of Inorganic Chemistry