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A Highly Stable Cd(Ⅱ) Coordination Polymer for Detection of Roxithromycin and B4O72-
Author NameAffiliationE-mail
WANG Ji-Jiang Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China yadxwjj@126.com 
WANG Lao-Bang Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
YUE Er-Lin Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
LI Jin-Feng Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
BAI Chao Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
TANG Long Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
WANG Xiao Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
HOU Xiang-Yang Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
ZHANG Yu-Qi Yan'an City Key Laboratory of New Energy & New Functional Materials, Shaanxi Key Laboratory of Chemical Reaction Engineering, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, China  
Abstract: A stable coordination polymer, [Cd2(L) (bpb) (H2O)4] ·0.5H4L (1) (H4L=1, 1'-ethylbiphenyl-3, 3' , 5, 5'-tetracarboxylic acid, bpb=1,4-di(pyridin-4-yl) benzene), were successfully constructed under solvothermal conditions. 1 exhibited excellent stability in different organic solvents and water. 1 could detect roxithromycin (ROX) and B4O72- in water by fluorescence quenching, and the detection limits were 0.21 and 1.59 μmol·L-1, respectively. 1 could be successfully used for the determination of ROX and B4O72- in Yanhe River water. Moreover, the possible sensing mechanisms are also discussed in detail.
Keywords: roxithromycin  B4O72-  fluorescence sensor  coordination polymer
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WANG Ji-Jiang,WANG Lao-Bang,YUE Er-Lin,LI Jin-Feng,BAI Chao,TANG Long,WANG Xiao,HOU Xiang-Yang,ZHANG Yu-Qi.A Highly Stable Cd(Ⅱ) Coordination Polymer for Detection of Roxithromycin and B4O72-[J].Chinese Journal of Inorganic Chemistry,2022,38(12):2491-2498.
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Chinese Journal of Inorganic Chemistry