| 希土烯丙基化合物的合成——Ⅱ.镥、钆的烯丙基化合物的合成 |
| SYNTHESES OF RARE EARTH-ALLYL COMPOUNDS—II. ALLYL COMPOUNDS OF GADOLINIUM AND LUTECIUM |
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| 摘要: 本文合成了两个新的对空气极敏感的希土烯丙基化合物,由无水希土氯化物与希丙基锂在四氢呋喃—乙醚中反应制得。产物经元素分析、红外光谱等确定其组成为:Li2Ln(C3H5)5·3Dioxane(Ln=Gd,Lu)。 |
| 关键词: 希土 钆 镥 烯丙基化合物 |
| 基金项目: 中国科学院科学基金 |
| Abstract: Two new rare earth-allyl compounds,which are very sensitive to air and moisture,have been synthesized by the reaction of the anhydrous lanthanide chloride with allyl-lithium in THF-ether solution.The compounds having the general formula Li2Ln(C3H5)63 Dioxane (Ln=Gd,Lu) were characterized by elemental analyses and their infrared spectra. |
| Keywords: rare earth gadolinium lutetium allyl compound |
| 投稿时间：1985-03-12 |
| 摘要点击次数: 1653 |
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| 邱文杰,黄祖恩,庄善明,吴文玲.希土烯丙基化合物的合成——Ⅱ.镥、钆的烯丙基化合物的合成[J].无机化学学报,1985,1(1):173-174. |
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