| PMTFP与中性磷萃取剂对钇(Ⅲ)的协同萃取 |
| SYNERGISTIC EXTRACTION OF YTTRIUM(Ⅲ)WITH 1-PHENYL-3-METHYL-4-TRIFLUOROACETYL-PYRAZOL-ONE-5 AND NEUTRAL ORGANOPHOSPHORUS EXTRACTANTS |
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| 摘要: 本文用萃取法测定了(Ⅰ)Y(Ⅲ)/0.5MNaClO4/PMTFP-C6H6和(Ⅱ)Y(Ⅲ)/0.5MNaClO4/PMTFP-TBP-C6H6及(Ⅲ)Y(Ⅲ)/0.5MNaClO4/PMTFP-TOPO-C6H6体系的萃取平衡常数和协苹平衡常数,结果如下: 体系(Ⅰ)的1gK30=-3.36;体系(Ⅱ)的1gK32=4.47; 体系(Ⅲ)的1gK31=6.65、1gK32=9.08。 |
| 关键词: 钇1-苯基-3-甲基-4三氟乙酰基吡唑铜-(5) |
| 基金项目: 中国科学院科学基金资助项目 |
| Abstract: The extraction of yttrium(Ⅲ) from perchloric acid solutions into mixtures of l-phenyl-3-methyl-4-trifluoroacetyl-pyrazol-one-5 (PMTFP) and neutral organophosphorus extractants, e. g. tri-n-butylphosphate (TBP) or tri-n-octylphosphinoxide(TOPO), in benzene has been studied.The formula of the extracted species have been shown to be YA3 S and YA3 2S (where HA = PMTFP, S = TBP, TOPO), and their equilibrium constants have been calculated. It is found to be greater for such mixtures than the either component alone. |
| Keywords: yttrium 1-phenyl-3-methyl-4-trifluoroacetyl-pyrazol-one-5 |
| 投稿时间：1985-06-05 |
| 摘要点击次数: 1646 |
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| 章惠农,乐嘉薇,张华麟.PMTFP与中性磷萃取剂对钇(Ⅲ)的协同萃取[J].无机化学学报,1986,2(1):70-77. |
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