| 钛β-二酮螯合物的合成 |
| SYNTHESIS OF TITANIUM B-DIKETOCHELATES |
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| 摘要: 合成了七种不同配体的β-二酮钛螯合物。化合物Ⅰ、Ⅱ、Ⅶ已有报导。Ⅲ、Ⅳ、Ⅴ、Ⅵ为文献未见报导的新化合物。Ⅶ虽已有报导,但该化合物是由我们自己研究的新方法合成的。X光衍射确定了该化合物的结构为:(OEt)2Ti[OC(CF3)=CHCOPh]2。通过元素分析、红外、核磁、质谱表征了所有合成的化合物。 |
| 关键词: 钛 β-二酮螯合物 |
| 基金项目: |
| Abstract: Seven titanium B-diketochelates were synthesized, among them # I, Ⅱ and Ⅶ were reported in literature, while # Ⅲ, Ⅳ, Ⅴand Ⅵ were not yet reported. Compound Ⅶ was synthesized by method different from previously reported, and its crystal molecular structure has been determined by the X-ray diffraction method to be (OEt)2Ti[OC(CF3)=CHCOPh]2. All chelates were characterized by elemental analysis, IR, NMR and MS spectra. |
| Keywords: titanium B-diketoehelate |
| 投稿时间：1986-01-09 |
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| 范秀菊,冯霄,陈光明,王积涛,缪方明,王瑾玲.钛β-二酮螯合物的合成[J].无机化学学报,1986,2(4):59-65. |
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