| 四硫氰合钴(Ⅱ)酸钡的18-冠-6配合物的研究 |
| STUDIES ON COMPLEX OF BARIUM TETRATHIOCYANATOCOBALTATE(Ⅱ)AND 18-CROWN-6 |
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| 摘要: 制备了四硫氰合钴(Ⅱ)酸钡的18—冠—6配合物,确定了它的组成,对它进行了红外光谱、质谱、热分析等多项物现性能的测试,并将测试结果结合已测定的配合物的结构进行了讨论. |
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| Abstract: The title stoichiometric complex has been prepared in a gel column of 18-crown-6 and tested by infrared, mass spectra, thermal analywes as well as other physical characters. The testing results and determined structures of the complex have been discussedThe red shiff of C-O-C stretching vibration frequencies in IR indicated the coordination of the crown ether. The [M1-1]+ and [M1+1]+ peaks from the crown parent M1+, the M2+ parent peak and [M2+2]+ peak of tetrathiocyanatocobalt group present all in MS of the complex. By thermal analyses, DTA, TG and DTG curves of the complex its loss of water, phase change and thermal decomposition were discussed. |
| Keywords: crown ether complex cobalt complex |
| 投稿时间：1986-05-16 |
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| 张文兴,王秀文,樊悦朋.四硫氰合钴(Ⅱ)酸钡的18-冠-6配合物的研究[J].无机化学学报,1987,3(3):33-37. |
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