| 二芳基汞的合成 |
| PREPARATION OF DIARYLMERCURY |
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| 摘要: 将氯化重氮苯的溶液加入氯化汞、维生素C、丙酮和少量氯化铜的混合物中,得到80%的氯化苯汞;如在反应混合物中补加维生素C、氯化铜和浓氨水,则得到二苯汞.用同样的方法制备了其他的二芳基汞,并讨论了反应可能的机理. |
| 关键词: 二芳基汞 维生素C 氯化亚汞 重氮盐 |
| 基金项目: |
| Abstract: Phenylmercuric chloride was obtained in 80% yield by adding ben-zeaediazonium chloride solution to a mixture of mercuric chloride, ascorbic acid, acetone and a small amount of cupric chloride. When the reaction mixture was treated with ascorbic acid, cupric chloride and ammonia diphenylmercury was formed. The same method was used for the preparation of other diarylmercury. The possible mechanism of this reaction was also discussed. |
| Keywords: diarylmercury ascorbic acid mercurous chloride diazonium salt |
| 投稿时间：1986-08-29 |
| 摘要点击次数: 1336 |
| 全文下载次数: 1389 |
| 王千杰,胡宏纹.二芳基汞的合成[J].无机化学学报,1987,3(3):78-81. |
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