| (η5-C5H5)2NdCl·OC4H8配合物的电子结构研究 |
| ELECTRONIC STRUCTURE OF COMPLEX(η5-C5H5)2NdC1·OC4H8 |
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| 摘要: (η5—C5H5)2NdCl·OC4H8配合物是带有离子性的共价化合物,易通过氯桥形成二聚物.讨论了配位活化与电子结构的关系及化学键性质. |
| 关键词: 钕 环戊二烯 配合物 电子结构 |
| 基金项目: |
| Abstract: The electronic structure of the complex(η5-C5H5)2NdC1·OC4H8 has been studied by an unrestricted INDO program. The results show that the species is covalent with some ionic character. The dimerization of the complex via bridging chlorine atoms is explained based on the composition and character of the frontier molecular orbitals. The coordination activation of Nd-Cl bond and ligand bonds is discussed by comparison between the bond orders before and after coordination. |
| Keywords: neodymium cyciopentadien complex electronic structure |
| 投稿时间：1986-06-30 |
| 摘要点击次数: 1619 |
| 全文下载次数: 1047 |
| 李振详,陈文启,倪嘉缵,徐光宪,任镜清.(η5-C5H5)2NdCl·OC4H8配合物的电子结构研究[J].无机化学学报,1987,3(3):111-114. |
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