| 芳香胺及其氮氧化物合希土配合物的研究 V.2, 2'—联喹啉—N, N'—二氧化物合硝酸希土固体配合物的合成及其性质 |
| STUDIES ON RARE EARTH COMPLEXES WITH HETEROCYCLIC AROMATIC AMINE AND THEIR N-OXIDE V. SYNTHESIS AND "CHARACTERlZATlON OF SOLID COMPLEXES OF RARE EARTH NITRATES WITH 2, 2'-BIQUINOLINE-N, N'-DIOXIDE |
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| 摘要: 在无水乙醇和氯仿混合溶剂中使重希土硝酸盐与2,2′—联喹啉—N,N′—二氧化物(BiqO2)作用,制得了固体配合物Ln(BiqO2)(NO3)3·2H2O(Ln=Tm,Yb,Lu,Y).通过元素分析、X光粉末衍射物相分析、差热—热重分析、红外光谱、紫外光谱、溶解性及摩尔电导测定,研究了配合物的组成及其有关性质. |
| 关键词: 硝酸铥 镱 镥和钇2-2′—联喹啉—N,N′—二氧化物 希土配合物 |
| 基金项目: |
| Abstract: The new solid complexes Ln(BiqO2)(NO3)3·2H2O(Ln-Tm, Yb, Lu, Y and BiqO2=2, 2'-biquinoline-N, N'-dioxide)have been synthesized using nonaqueous ethanol and chloroform as reaction medium. These complexes have been characterized by elemental analyses, X-ray powder diffraction, differential thermal analyses(DTA), thermogravimetry(TG), infrared spectra, ultraviolet spectra and molar conductances. |
| Keywords: thulium ytterbium lutetium and yttrium nitrates 2,2'bi-quinoline-N N'-dioxide lanthanide complexes |
| 投稿时间：1986-05-14 |
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| 袁景利,课民裕,甘新民.芳香胺及其氮氧化物合希土配合物的研究 V.2, 2'—联喹啉—N, N'—二氧化物合硝酸希土固体配合物的合成及其性质[J].无机化学学报,1987,3(4):20-27. |
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