| 钴希夫碱配合物及其分子氧加合物的合成与表征 |
| SYNTHESIS AND CHARACTERIZATION OF COBALT SCHIFF BASE COMPLEXES AND THEIR CARRYING OXYGEN ADDUCTS |
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| 摘要: 以β-萘酚醛与一系列二胺缩合为配体,合成了钴的配合物。通过测定配合物在各种溶剂中吸收的氧气,得到了配合物与分子氧的摩尔比。并从各种溶剂中分离出了一系列2:1和1:1(Co/O2)的分子氧加合物。对这些配合物和分子氧加合物进行了元素分析,红外、紫外一可见光谱和磁化率的表征,并研究了性质与结构的关系。 |
| 关键词: 钴配合物 Schiff碱配合物 分子氧加合物 |
| 基金项目: |
| Abstract: Some coordination compounds of cobalt with Schiff base, derived by the condensation of 2-hydroxy-1-naphthaldehyde with a series of diamines have been syntheized. The ratio of cobalt/oxygen is determined by gas-volumetric measurements for absorbed oxygen. Several 2:1 and 1:1 adducts of cobalt schiff base complexes with molecular oxygen have been isolated from various solvents. All these compounds are characterized by elemental analysis, IR, UV-visible spectra and magnetic susceptibility. The relationship between properties and structures is studied. |
| Keywords: cobalt complex schiff base complex molecular oxygen adducts |
| 投稿时间：1987-04-14 |
| 摘要点击次数: 1937 |
| 全文下载次数: 1431 |
| 戴寰,李进,韩志坚,陈汉文.钴希夫碱配合物及其分子氧加合物的合成与表征[J].无机化学学报,1988,4(1):61-67. |
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