| 在三乙酸锰引发下芳烃与β-二羰基化合物的反应 |
| MANGANESE(Ⅲ) ACETATE INITIATED REACTION OF AROMATIC HYDROCARBONS WITH β-DICARBONYL COMPOUNDS |
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| 摘要: 在三乙酸锰和磷酸作用下,芳烃和乙酰乙酸乙酯反应,生成芳基乙酰乙酸乙酯和亚芳基二乙酰乙酸乙酯。反应是通过生成CH3COCHCO2C2H5自由基进行的。丙二酸二乙酯和芳烃在三乙酸锰和磷酸作用下也能发生同样的反应。 |
| 关键词: 三乙酸锰 稠环芳烃 β-二基化合物 |
| 基金项目: |
| Abstract: In the presence of Mn(OAc)3 and H3PO4 treatment of aromatic hydrocarbons with acetoacetate produces ethyl arylacetoacetates and diethyl arylidenediacetoacetates by the way of homolytic substitution involving the CH3COCHCO2C2H5 radical. The reaction of malonic ester with aro-matics can also be carried out by above reagents. |
| Keywords: manganese(Ⅲ) acetate aromatic hydrocarbon β-dicarbonyl compound |
| 投稿时间：1987-06-29 |
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| 陈伟兴,席尚忠,胡宏纹.在三乙酸锰引发下芳烃与β-二羰基化合物的反应[J].无机化学学报,1988,4(1):77-82. |
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