| 3,6-二-〔二甲氨基〕二苯并碘六环六硝酸钍配合物的研究 |
| STUDY ON SALT OF 3,6-DI-(DIMETHYLAMINO)-DIBENZOPYRIODONIUM THORIUM HEXANITRATE |
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| 摘要: 本文报道了在甲醇介质中以硝酸钍和碘杂环硝酸盐为原料合成了3,6—二—〔二甲氨基〕二苯并碘六环六硝酸钍配合物。 |
| 关键词: 钍 二苯并碘六环 |
| 基金项目: |
| Abstract: It has been reported here that thorium nitrate reacted with 3,6-di-(dimethylamino)-dibenzopyriodonium nitrate in methanol to produce 3,6-di-(dimethylamino)-dibenzopyriodonium thorium hexanitrate. We have studied its properties by use of IR, TGA, DSC, UV,1H-NMR and X-ray powder diffraction etc. IR differences between the new compound and (NH4)2Th(NO3)6, Cs2Th(NO3)6, have been compared and the position of the ligand NO3- in new compound has also been discussed. The new compound is sensitive to heat and light, easily changing to violet colour. |
| Keywords: thorium dibenzopyriodonium |
| 投稿时间：1987-02-06 |
| 摘要点击次数: 1318 |
| 全文下载次数: 1111 |
| 王初华,陈淑英.3,6-二-〔二甲氨基〕二苯并碘六环六硝酸钍配合物的研究[J].无机化学学报,1988,4(2):42-49. |
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