| CaClH2PO4·H2O的合成及其性质的研究 |
| STUDIES ON SYNTHESIS AND CHARAC-TERIZATION OF CaClH2PO4·H2O |
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| 摘要: 本文介绍了CaClH2PO4·H2O的合成和纯化的方法。用精密量热计系统测定了CaClH2PO4·H2O的标准生成焓在298.15K时为-2282.34kJ mol-1。评述和讨论了热分解反应的化学动力学性质,测定了分解反应的级数和表现活化能。 |
| 关键词: 氯化磷酸-钙 标准生成焓 热分解反应 |
| 基金项目: |
| Abstract: In this paper, the synthesis and purification was described for the monocalcium chlorophosphate. By using precision calorimeter system, the standard enthalpy of formation of CaClH2PO4·H2O at 298.15 K was determined to be - 2282.34 kJ·mol-1. The Chemical kinetics properties of thermal reaction, including the order of reaction and apparent activation energy, have been described and discussed. |
| Keywords: monocalcium chlorophosphate standard enthalpy of formation thermal decomposition reaction |
| 投稿时间：1987-05-04 |
| 摘要点击次数: 1360 |
| 全文下载次数: 1441 |
| 武世界,汪存信,刘剑彤,屈松生.CaClH2PO4·H2O的合成及其性质的研究[J].无机化学学报,1988,4(3):47-54. |
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