| 离子水化模型和水化能的计算 |
| MODEL OF IONIC HYDRATE AND CALCU-LATION OF HYDRATION ENERGY |
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| 摘要: 本文根据静电理论和晶体场理论将金属离子的水化分为水合和水溶剂化两个过程,水化能主要决定于这两个过程的能量变化,并由此推得水化能的计算公式。计算结果与实验值基本相符,从而证明这一模型是合理的。 |
| 关键词: 离子水化 水化能 |
| 基金项目: |
| Abstract: When an ion of metal is hydrated, the process can be divided into two steps: the hydration and solvation according to the static electricity theory and the crystal field theory.The hydration energy is mainly depended on the change of energy in these two steps.As a consequence its formula calculated can be derived.The results obtained are in agreement with the experimental values, thus the rationality of this model is proved . |
| Keywords: ion hydration hydration energy |
| 投稿时间：1987-07-24 |
| 摘要点击次数: 1685 |
| 全文下载次数: 2319 |
| 杨世辉,吴根华.离子水化模型和水化能的计算[J].无机化学学报,1988,4(4):124-129. |
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