| Schiff碱配合物的研究——Ⅰ.若干Fe(Ⅲ)—五齿配体配合物的合成与表征 |
| STUDIES ON SCHIFF BASE COMPLEXES——Ⅰ.SYNTHESIS AND CHARACTERIZATION OF SOME IRON(Ⅲ) COMPLEXES WITH PENTACOORDINATE LIGANDS |
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| 摘要: 合成若干五齿Schiff碱配体与Fe(Ⅲ)的配合物,以红外光谱、紫外一可见光谱、1H核磁共振以及Mössbauer谱等手段研究其性质。结果表明,Schiff碱与Fe(Ⅲ)配位后,NO3-以单齿形式与铁键合,所有配合物呈高自旋态,未观察到强反铁磁性偶合。 |
| 关键词: Schiff碱 Fe(Ⅲ) 五齿配体 |
| 基金项目: |
| Abstract: Several Iron(Ⅲ) complexes with pcntacoordinate Schiff base ligands have been prepared and their properties characterized by IR,UV-Vis,1HNMR,and Mössbauer spcctroscopic techniqucs.The results indicate that the nitrate complexes appear to have monodcndate bound nitrate,and the nitrate can be replaced by a hydroxy group to form hydroxy complexes rather than μ-oxo compounds. No noticeable antifcrromagnetic interaction in solution or solid state was found,and all of the complexes are in a high-spin state. The Mb'ssbaucr parcmctcrs have also been explained. |
| Keywords: schiff base Fe(Ⅲ) pentacoordinate |
| 投稿时间：1987-12-24 |
| 摘要点击次数: 1510 |
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| 汪信,M. E. Kotun,J. C. Fanning.Schiff碱配合物的研究——Ⅰ.若干Fe(Ⅲ)—五齿配体配合物的合成与表征[J].无机化学学报,1989,5(2):1-7. |
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