| 含螯合配位体的M-Fe-S系列簇合物的合成,结构和性质研究(M=Mo,W) |
| STUDY ON SYNTHESIS, STRUCTURE AND PROPERTIES OF A SERIES OF M-Fe-S CLUSTER COMPOUNDS CONTAINING CHELATE GROUP |
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| 摘要: 本文总结报道了(1) [Et4N]3[Mo2FeS6(SCH2CH2S)2],(2) [Et4N]3[W2FeS6(SCH2CH2S)2]2(3) {[Et4N]3[Mo2FeS6(SCH2-CH2S]2}4·CH3CN和(4) [Et4N]4[Mo2Fe4S9(SCH2CH2S)2]四种簇合物的合成,结构和性质研究。在Nicolet R3 System四圆单晶衍射仪上,用MoK辐射收集数据,用SHELXTL程序,重原子法解出这些簇合物的晶体结构,用红外光谱、紫外可见光谱和穆斯堡尔谱对簇合物进行了物理性质的测定.同时用循环伏安法对簇合物的氧化还原特性也进行了研究,并结合量子化学计算探讨了簇合物的电子结构和性能之间的关系。 |
| 关键词: 簇合物 钼 钨 铁 硫 |
| 基金项目: |
| Abstract: In this paper,the synthesis,structure and properties of four type cluster compounds,(1) [Et4N]3[Mo2FeS6(SCH2CH2S)2](2)[Et4N]3[W2FeS6(SCH2CH2S)2],(3){[Et4N]3[Mo2FeS6(SCH2CH2S)2]}4·CH3CN and (4) [Et4N]4[Mo2Fe4S9(SCH2CH2S)J are reported. The crystal structure of these cluster compounds had been determined by X-ray method. The data of diffractional intensities of single crystals were obtained on a four-circle auto-diffractomer with MoKa radiation (Nicolet R3system) and the structure was worked out by the method of heavy atom using SHELXTL programme. The physical properties of these cluster compounds had been determined with IR,UV-Visible and Mossbauer spectra,simultaneously,the redox characteristics of these cluster componds had been studied with cyclic voltammetric method and the problem of electronic structure of these cluster compounds was discussed in combination with quantum-chemical calculations. |
| Keywords: cluster molybdenum tungsten iron sulphur |
| 投稿时间：1987-09-05 |
| 摘要点击次数: 1210 |
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| 张致贵,孙文涛,牛淑云,李淑芹,叶玲,樊玉国,郭纯孝.含螯合配位体的M-Fe-S系列簇合物的合成,结构和性质研究(M=Mo,W)[J].无机化学学报,1989,5(4):35-42. |
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