| 18-冠-6六硫氰酸根合铟(Ⅲ)酸钾配合物的分子和晶体结构 |
| MOLECULAR AND CRYSTAL STRUCTURE OF 18-CROWN-6 POTASSIUM WITH INDIUM(Ⅲ) THIOCYANATES COMPLEX |
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| 摘要: 对标题配合物{[K(C12H24O6)][K[(C12H24O6)(H2O)]2}{In(NCS)6)·2H2O的单晶进行了X-射线结构分析。 |
| 关键词: 冠醚配合物 铟(Ⅲ)配合物 晶体结构 |
| 基金项目: |
| Abstract: The title crystal belongs to monoclinic system,space group is C2/c with a =12.758(2),b=24.360(6),c=22.026(3)Å,β=92.13(1)° ,Z=4. The structure was determined by heavy-atom techniques and AF syntheses,and then refined by full-matrix least-squares method. The final value of R is 0.046.The indium(Ⅲ) ion coordinates with six iso-thiocyanates to form an octahedral complex anion. Each of three potassium ions in a complex molecule coordinates with its crown molecule to form an 1:1 complex cation. Only two of them contain a coordinate water molecule,respectively,which combinates own crystal water through hydrogen bond. |
| Keywords: crown complex indium(Ⅲ) complex crystal structure |
| 投稿时间：1987-12-19 |
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| 展守棠,樊悦朋,王秀文,张文兴.18-冠-6六硫氰酸根合铟(Ⅲ)酸钾配合物的分子和晶体结构[J].无机化学学报,1989,5(4):109-112. |
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