| 二芳基硼螯合物的配体取代反应 |
| LIGAND SUBSTITUTION REACTION OF DIARYLBORON CHELATES |
|
| 摘要: 本文通过一系列配体取代反应证实氨基乙醇、氨基酸、2-(α-羟基苄基)苯骈咪唑(HBB)、8-羟基喹啉(8-HQ)等N,O双齿配体与二芳基硼的螯合能力存在下列强弱顺序: 8-HQ >HBB >NH2CH2CH2OH > RCH(NH2)COOH相应螯合物的稳定性也依此序递降,有关四配位二芳基硼螯合物可按这一规律直接进行转化。 |
| 关键词: 硼化合物 螯合物 配体 取代反应 |
| 基金项目: |
| Abstract: Through a series of ligand substitution reactions, the chelating abilities of ethanolamine, amino acids, 2-(α-hydroxybenzyl)bcnzimidazoIe(HBB), 8-hydroxy quinoline(8-HQ) to diarylboron moiety were observed in a decreasing:8-HQ > HBB > NH2CH2CH2OH > RCH(NH2)COOH The corresponding stabilities of diarylboron chelates therefore decrease in the same order and the chelate with a weak ligand could be converted to a chelate with a strong ligand according to this order. |
| Keywords: boron compound chelate ligand substitution reaction |
| 投稿时间：1988-02-13 |
| 摘要点击次数: 1406 |
| 全文下载次数: 1317 |
| 袁国正,蒋明亮,张国敏.二芳基硼螯合物的配体取代反应[J].无机化学学报,1990,6(3):314-318. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
