| 铜(Ⅱ)与2-[(邻羟苄叉)胺基]酚和吡啶混配型配合物的合成、性质和结构 |
| SYNTHESIS, PROPERTIES AND STRUCTURE OF MIXED LIGAND COORDINATION OF COPPER(II) WITH 2-[(o-HYDROXYBENZYLIDENE)AMINO] PHENOL AND PYRIDINE |
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| 摘要: 本文合成了铜(Ⅱ)与2-[(邻羟苄叉)胺基]酚和吡啶混配型配合物。通过四园衍射仪测定了配合物的结构。晶体属正交晶系,空间群为Pna21。晶胞参数:α=9.808(1)Å,b=11.430(3)Å,c=13.436(2)Å,V=1506.2Å3,Z=4,Dc=1.56/cm3,用DTA和TG技术对配合物的热分解过程进行了研究。 |
| 关键词: 铜 配合物 合成 性质 结构 |
| 基金项目: |
| Abstract: The mixed ligand coordination of Cu(II) with 2-[(σ-hydroxybenzylidene)amino] phenol and pyridine has been synthesized. The structure of the coordination was determined by means of four cycle diffractometer. The crystal is orthorhombic, space group Pna21,. The parameters of crystal cell are: α= 9.808(1)Å, b= 11.430(3)Å, c= 13.436(2)Å, P=1506.2Å3, Z = 4, De= 1.56g/cm3.The processes of thermal decomposition of the coordination have been investigated by DTA and TG techniques. |
| Keywords: copper coordination compound symthesis property structure |
| 投稿时间：1988-03-07 |
| 摘要点击次数: 1476 |
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| 刘德信,崔学桂,李凤玲.铜(Ⅱ)与2-[(邻羟苄叉)胺基]酚和吡啶混配型配合物的合成、性质和结构[J].无机化学学报,1990,6(3):324-328. |
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