| 1,1-二氰乙烯基-2,2-二硫醇盐第一过渡系列金属配合物的研究 Ⅱ.钒(Ⅳ)和铁(Ⅲ)配合物的研究 |
| RESEARCH ON THE FIRST-ROW METAL COMPLEXES CONTAINING 1,1-DICYANOETHYLENE-2,2-DITHIOLATE II.SYNTHESES AND SPECTRA OF Fe(Ⅲ) AND V(IV) COMPLEXES |
|
| 摘要: 文献中研究了1,1-二氰乙烯基-2,2-二硫醇盐(简称i-mnt)的Cu(Ⅱ)和 Ni(Ⅱ)配合物.现合成出i-mnt的钒(Ⅳ)和铁(Ⅲ)配合物,根据钒(Ⅳ)配合物的ESR谱和铁(Ⅲ)配合物的Mossbauer谱及其他光谱探讨它们的键合和结构。 |
| 关键词: 2,2-二硫醇盐 钒(Ⅳ)配合物 铁(Ⅲ)配合物 |
| 基金项目: |
| Abstract: Fe(Ⅲ) and V(IV) coordination compounds containing 1,1-cyanoethylene-2,2-dithiolate (abbr. as i-mnt) were synthesized. They were characterized by elemental analyses, magnetic susceptibilities, infrared spectra and UV-spectra measurements. Fe(Ⅲ) and V(IV) complexes were researched by Mossbauer spectrum and ESR spectrum respectively. The results indicated that Fe(Ⅲ) complex is dimeric, and V(IV) complex is monomeric. |
| Keywords: 2,2-dithlolate vanadism(IV)eomplex Iron(Ⅲ)complex |
| 投稿时间：1988-04-14 |
| 摘要点击次数: 1120 |
| 全文下载次数: 1212 |
| 沈斐凤,耿志明,倪亚萍.1,1-二氰乙烯基-2,2-二硫醇盐第一过渡系列金属配合物的研究 Ⅱ.钒(Ⅳ)和铁(Ⅲ)配合物的研究[J].无机化学学报,1990,6(3):347-349. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
