| [Cu(H2O)(phen)2](CIO4)2的晶体结构 |
| CRYSTAL STRUCTURE OF MONOAQUOBIS (1,10-PHENANTHROLINE) COPPER(II) CHLORATE |
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| 摘要: 标题化合物晶体属三斜晶系;空间群为P1;晶胞参数:a=8.182(2)Å,b=10.389(2)Å,c=16.261(5)Å,α=99.38(2)°,β=89.97(2)°,γ=113.18(2)°;Z=2,两个phen上的四个N原子和一个配位水中的O原子围绕中心体Cu原子形成一个畸变的三角双锥构型,配位水与阴离子ClO4-中的O原子形成氢键。 |
| 关键词: [Cu(H2O)(phen)2](ClO4)2 晶体结构 |
| 基金项目: |
| Abstract: The crystal structure of the title compound has been determinated by X-ray diffraction method. The crystal is triclinic with following parameters: a=8.182(2)Å, b= 10.389(2)Å, c=16.261(5)Å, a = 99.38(2)°, β=89.97(2)°, r= 113.18(2)°; space group P1, Dc=1.702gcm-3, Z=2. The structure was refined by least-square technique to a final R of 0.075. The molecule is composed of [Cu(H2OXphen)]2+ cation and ClO4- anion. The copper atom is surrounded by four nitrogen atoms of the two phenanthroline ligands (average Cu-N=2.043Å) and a water-oxygen atom (Cu-O = 2.44Å) in a distorted trigonal-bipyramidal arrangement in which the equatorial plane is composed of Cu, two N and water O atoms, and the axial positions are occupied by other two N atoms. |
| Keywords: monoaquobis(1|10-phenanthroline)copper(II) chlorate crystal structure |
| 投稿时间：1988-05-11 |
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| 王尧宇,高忆慈,史启祯,祝英,王欣.[Cu(H2O)(phen)2](CIO4)2的晶体结构[J].无机化学学报,1990,6(3):350-352. |
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