| Schiff碱型大环配合物的合成及性质研究 |
| SYNTHESES AND PROPERTIES OF SCHIFF'S BASE MACROCYCLIC COMPLEXES |
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| 摘要: 本文合成了一个新的Schiff碱型大环配体“三氧二氮”(L),及其Cu(Ⅱ)、Ce(Ⅱ)、Ni(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)、Ag(Ⅰ)的配合物,经红外光谱、电导、元素分析等推算了它们的组成并指认了谱带的归属.对Cu(Ⅱ)配合物进行了电子顺磁共振谱、光电子能谱分析. |
| 关键词: Schiff碱大环 铜锌钴镍镉银 配合物 合成 性质 |
| 基金项目: 国家自然科学基金资助的课题 |
| Abstract: A new Schiff's base macrocyclic compound(L)has been synthesized and characterized by elemental analyses, IR, MS.The complexes of Cu(Ⅱ), Co(Ⅱ). Ni(Ⅱ), Zn(Ⅱ), Cd(Ⅱ). Ag(Ⅰ)with L arc isolated. The complexes were characterized by elemental analyses, IR, electrical conductance. The ESR properties of Cu(Ⅱ)complex has been studied, and XPS of Cu(Ⅱ)complex indicates that the coordination ability of N in L is stronger than that of O. |
| Keywords: Schiff's base maeroeyelie eoinpoand Cu Co Ni Zn Cd Ag complex synthesm property |
| 投稿时间：1988-10-06 |
| 摘要点击次数: 1424 |
| 全文下载次数: 1194 |
| 雷秀斌,季振平,萧文锦,李洪仪,莫少波.Schiff碱型大环配合物的合成及性质研究[J].无机化学学报,1991,7(3):253-256. |
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