| 四苯硼酸盐的热化学研究——Ⅱ.一价四苯硼酸盐的标准生成焓 |
| STUDIES ON THERMOCHEMISTRY OF TETRAPHENYLBORATES Ⅱ.STANDARD ENTHALPIES OF FORMATION OF UNIVALENT TETRAPHENYLBORATES |
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| 摘要: 本文用自行建立的精密溶解层热装置测定了298.15K时,NH4BPh4、KBPH4、RbBPh4、CsBPh4、TlBPh4、AgBPh4和HgPh2七种沉淀反应的反应焓,由此计算了一价四苯硼酸盐的标准生成焓、熵及吉布斯自由能. |
| 关键词: 四苯硼酸盐 热化学 反应焓 标准生成焓 |
| 基金项目: |
| Abstract: Using precision solution calorimeter constructed in this laboratory, the enthalpies of reaction of seven precipitates of NH4BPh4、KBPH4、RbBPh4、CsBPh4、TlBPh4、AgBPh4 and HgPh2 had been determined at 298.15 K. Further, the standard enthalpies, entropies and Gibbs free energies of formation of univalent tetraphenylborates had been calculated at 298.15 K. |
| Keywords: tetraphenylborate thermocbemistry reaction enthalpy standard enthalpy of formation |
| 投稿时间：1989-07-21 |
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| 张忠海,邹立壮,徐桂端,屈松生.四苯硼酸盐的热化学研究——Ⅱ.一价四苯硼酸盐的标准生成焓[J].无机化学学报,1991,7(4):486-489. |
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