香草醛异烟酰腙与钴、镍、铜、锌和镉配合物的合成和性质研究
SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF VANILLIN ISONICOTINOYL HYDRAZONE WITH Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ) AND Cd(Ⅱ)
作者单位
王明雄 湖北大学化学系, 武汉 430062 
邓汉芹 湖北大学化学系, 武汉 430062 
娄兆文 湖北大学化学系, 武汉 430062 
摘要: 本文合成了香草醛异烟酰腙(H2L)和邻香草醛异烟酰腙(H2L)与钴(Ⅱ)、镍(Ⅱ)、铜(Ⅱ)、锌(Ⅱ)和镉(Ⅱ)的九个新配合物:M(HL)2·nH2O[M(Ⅱ)=Co、Ni、Cu、Zn和Cd,n=0,2]和M(HL)2·nH2O[M(Ⅱ)=Co、Ni、Cu和Zn,n=0-3]。采用
关键词: 香草醛  邻香草醛  异烟肼  希夫碱配合物
基金项目: 
Abstract: Complexes of cobalt(Ⅱ), nickel(Ⅱ), coppcr(Ⅱ), zinc(Ⅱ) and cadmium(Ⅱ) with vanillin isonicotinoyl hydrazone and o-vanillin isonicotinoyl hydrazonc have been prepared and characterized by elemental analyses, IR spectra, molar conductance, magnetic measurements, electronic absorption spectra, powder X-ray diffraction and differential thermal analyses. The bonding and stereochemistry of the complexes arc discussed.
Keywords: vanillin  o-vanillin  isonicotinic hydrazide  Schiff base complex
投稿时间:1990-10-28 
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王明雄,邓汉芹,娄兆文.香草醛异烟酰腙与钴、镍、铜、锌和镉配合物的合成和性质研究[J].无机化学学报,1992,8(3):255-258.
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