| 对位取代四苯基卟啉及其铁(Ⅲ)配合物的~1H NMR研究 |
| 1H NMR STUDY ON PARA-SUBSTITUTED TETRAPHENYLPORPHYRINS AND FERRIC PORPHYRIN COORDINATION COMPOUNDS |
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| 摘要: 本文用BRUKER MSL-400型超导核磁共振仪,对于对位取代四苯基卟啉[H2(p-X)TPP,X=Cl,H,CH3,OCH3],对位取代四苯基卟啉铁(Fe(Ⅲ)(p-X)TPPCl)及其轴向配合物([Fe(Ⅲ)(p-X)TPP(HIm)2]+Cl-,([Fe(Ⅲ)(p-CH3)TPPYm] |
| 关键词: 1H NMR 对位取代四苯基卟啉 铁卟啉配合物 电子自旋离域机理 |
| 基金项目: 中国科学院波谱与原子分子物理实验室资助项目 |
| Abstract: Proton nuclear magnetic resonance spectra of H2(p-X)TPP, Fe(p-X)TPPCl, [Fe(p-X)TPP(HIm)2]+Cl- and other axial coordination compounds were recorded and analyzed systematically by means of BRUKER MSL-400 MHz superconducting nuclear magnetic resonance instrument. The molecular symmetry, electronic structure, paramagnetic effect and the spin-delocalization mechanism of iron porphyrins were discussed. |
| Keywords: 1H NMR H2(p-X)TPP ferric porphyrin coordination compound electronic spin-delocallzation mechanism |
| 投稿时间：1991-02-23 |
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| 夏新,朱志昂,陈荣悌.对位取代四苯基卟啉及其铁(Ⅲ)配合物的~1H NMR研究[J].无机化学学报,1992,8(4):367-372. |
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