| 金属羰基化合物的结构对氧原子转移反应速率的影响 |
| EFFECT OF STRUCTURAL FACTORS ON THE RATES OF OXYGEN ATOM TRANSFER TO METAL CARBONYLS |
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| 摘要: 本文研究了氧化三甲胺Me3NO与羰基簇合物M4(CO)12-nLn(M=Co,Ir;n=1,2;L=磷配体)的氧转移反应动力学,讨论了反应机理。 |
| 关键词: 羰基钴簇配合物 羰基铱簇配合物 氧原子转移反应 动力学与机理 |
| 基金项目: 国家自然科学基金 |
| Abstract: The comparative study on kinetics and mechanism was made to examine further the importance of CO bridging concept to the reactivity of metal clusters in the CO substitution by L of M4(CO)12-nLn(M=Co, Ir; L=phosphorous ligand; n=1,2) in the presence of Me3NO. Thesecond-order rate law and kinetic behavior arc the same as that reported earlier on such reaction and hence provide a common basis for comparision. The reaction rates of Ir compoundsare greater than those of corresponding Co compounds (Co3(CO)11L and theM3(CO)12 on studies earlier from different are here obtained results The paper. this in ligandsstudied phosphorous with Fe > Ru > Os and this was discussed in terms of the presumed important contributionof CO bridging to the rates of associative reactions in metal carbonyl clusters. Some other effects of structural factors on rates of the oxygen atom transfer to metal carbonyls were also discussed. |
| Keywords: cobalt carbonyl cluster iridium carbonyl cluster oxygen atom transfer reaction kinetics |
| 投稿时间：1992-11-28 |
| 摘要点击次数: 1104 |
| 全文下载次数: 1264 |
| 王建奇,高忆慈,王尧宇,史启祯.金属羰基化合物的结构对氧原子转移反应速率的影响[J].无机化学学报,1994,10(1):35-39. |
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