| 四苯氧基酞菁镁、锰、铝和锌的合成和性质 |
| SYSTHESIS AND PROPERTIES OF TETRAPHENYLOXY PHTHALOCYAMINATO MAGNESIUM, MANGANESE, ALUMINIUM AND ZINC |
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| 摘要: 合成了新的酞菁配合物4,4',4″,4″-四苯氧基酞菁镁[TPhOPcMg(Ⅱ)]、锰[TPhOPcMn(Ⅲ)Ac]、铝[TPhOPcAl(Ⅲ)Cl]、锌[TPhOPcZn(Ⅱ)]测定了它们的IR、UV-Vis光谱,在DMF中的氧化还原半波电势(E>1/2)、电子转移速度常数、在乙腈中的荧光性质及锰的配合物在不同电位下的光谱变化情况。 |
| 关键词: 酞菁 镁 锰 铝 锌 荧光 |
| 基金项目: 国家自然科学基金;江苏省教委自然科学基金 |
| Abstract: 4,4',4″,4″-tetraphenyloxyphthalocyaminoato magnesium [TPhOPcMg(Ⅱ)],manganese [TPhOPcMn(Ⅲ)Ac],aluminium[TPhOPcAl(Ⅲ)Cl] and zinc [TPhOPcZn(Ⅱ)] were synthesized.Their IR,UV-Vis,half-wave potentials(E1/2) and electron tranfer rate constants of the redox reactions for the complexes in DMF and fluorescent of complexes in CH3CN were measured. The change of UV-Vis spectra for TPhOPcMnAc was studied when electrolysed at different voltages. |
| Keywords: phthalocyanine manganese magnesium aluminium zinc fluorescent |
| 投稿时间：1993-04-26 |
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| 吴星,姚荣,潘兰,张国林,王葆生,陈忠.四苯氧基酞菁镁、锰、铝和锌的合成和性质[J].无机化学学报,1994,10(2):178-183. |
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