| 含氮茂铁异核金属配合物的合成和性质研究 |
| SYNTHESIS AND PROPERTIES STUDY OF THE CONTAIN NITROGEN FERROCENE HETERONUCLEAR ORGANO-METALLIC COORDINATION COMPOUNDS |
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| 摘要: Pd(Ⅱ)、Pt(Ⅱ)DMAF配合物已合成,并已定结构[1].本文采用MX2(M=Ni(Ⅱ),Co(Ⅱ),Zn(Ⅱ),Cu(Ⅱ);X=Cl,Br,Ⅰ)在CH2Cl2中和DMAF作用合成[MX2·2DMAF]型配合物。由NiCl2·2DMAF·C7H8晶胞参数推知属于对称链状四配位结构。IR谱表明,该化合物化学式为MX2·2DMAF.CV表明配合物中M(Ⅱ)和Fe(Ⅱ)存在。由于金属离子互相影响,Ep/2随M(Ⅱ)性质呈规律性变化。 |
| 关键词: 异核配合物 循环伏安法(CV) DMAF N－N－二甲基胺代甲基二茂铁 |
| 基金项目: 福建省自然资金资助 |
| Abstract: The compounds of [MX2·2DMAF] can be made in the neutral medium, such as CH2Cl2etc; (M=Ni(Ⅱ), Co(Ⅱ), Cu(Ⅱ), Zn(Ⅱ); X= Cl, Br,(Ⅰ).[NiCl2·2DMAF]·C7H8 can beCrystallizing in toluene, the metal atom M(Ⅱ) is on the crystallographic symmetry ccnter. TheirIR spectra were studied. The effect between M(Ⅱ) and Fe(Ⅱ) cause the change of Ep valuerigularly according to the characters of M(Ⅱ). |
| Keywords: keteronuclear coordination compound cyclic voltammetry N-N-dimethylaminomethyl-ferrocene |
| 投稿时间：1993-11-02 |
| 摘要点击次数: 966 |
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| 袁锡文,黄兆华.含氮茂铁异核金属配合物的合成和性质研究[J].无机化学学报,1994,10(3):324-328. |
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