| 配合物聚合反应研究──Ⅰ.以对氨基苯磺酸盐合成聚酰亚胺 |
| POLYMERIZATION OF COORDINATION COMPOUNDS Ⅰ.SYNTHESIS POLYIMIDES FROM DIVALENT METAL SALTS OF P-ANILINE SULFONIC ACID |
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| 摘要: 以对氨基苯磺酸的二价金属配合物为原料合成了一系列主链上含金同元素(Ca,Cu.Co,Mi)的聚酰亚胺。以元素分析、IR和固体13C-NMR对其组成及结构进行了表征,通过TG-DTA研究了其热性能,并讨论了含金属元素聚酰胺酸溶液的粘度与其中金属元素及其含量的关系 |
| 关键词: 对氨基苯磺酸配合物 合成 含金属元素聚酰亚胺 热性能 |
| 基金项目: 国家教委年轻教师基金 |
| Abstract: A class of novel metal-containing(Ca,Cu,Co,Ni)polyimides were obtained from the diamine-sulfonic coordination compounds and characterized by clemental analysis,IR,and solid 13C-NMR. The relationship between inherent viscosity of metal-containing polyamic.acids and metal content of polymer were examined, and the thermal properties of metal-containing polyimides were studied by TG-DTA. |
| Keywords: diamine-sulfonic coordination compound synthesis metal-containing polyimide thermal property |
| 投稿时间：1993-12-02 |
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| 仇武林,李灿,华万森,王瑛,陆路德,汪信.配合物聚合反应研究──Ⅰ.以对氨基苯磺酸盐合成聚酰亚胺[J].无机化学学报,1994,10(4):378-383. |
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