| Na1－xZr2－xNbxP3O12系列化合物的水热晶化研究 |
| HYDROTHERMAL CRYSTALLIZATION OF Na1-xZr2-xNbxP3O12 SERIES COMPOUNDS |
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| 摘要: 采用水热晶化反应,制备出传统需要高温固相反应合成的掺杂NASICON化合物Na1－xZr2-xNbxP3O12(02P3O12相同的结构.固体31PNMR研究证实Nb5+部分取代了Zr4+所在位置,参与骨架的组成,并统计分布于结构中.水热晶化产物与固相反应产物具有相同的离子电导性能. |
| 关键词: 水热晶化 离子导体 磷酸盐 |
| 基金项目: 国家自然科学基金 |
| Abstract: The doped NASICON compounds, Na1-xZr2-xNbxP3O12(02P3012. The studies of solid state 31PNMR proved that Nb5+.ions were partly substituted for Zr4+ ions in the crystal structure and participated in the form of the framework and distributed randomly in the crystalline frame-work. The compounds have the same ionic conductivity properties as the products prepared by solid-state reaction. |
| Keywords: hydrothermal crystallization ionic conductor phosphate |
| 投稿时间：1994-01-19 |
| 摘要点击次数: 1507 |
| 全文下载次数: 1955 |
| 岳勇,周凤岐,庞文琴,吕景才.Na1－xZr2－xNbxP3O12系列化合物的水热晶化研究[J].无机化学学报,1995,11(1):19-23. |
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