| 含硫、氮Schiff碱配合物—二水二分之一二甲基亚砜醋酸四邻香草醛缩胺基硫脲合镉(Ⅱ)的合成及晶体结构 |
| SYNTHESIS AND CRYSTAL STRUCTURE OF THE TRINUCLECADMIUM COMPLEX Cd3[CH3O(O)C6H3CH=NNHC(S)NH2]4·(CH3COO)2·1/2[CH3S(O)CH3]·2H2O |
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| 摘要: X射线单晶衍射结果表明,三核镉配合物Cd3[CH3O(O)C6H3CH=NNHC(S)NH2]4·[CH3COO]2·1/2[CH3S(O)CH3]·2H2O为单斜晶系,空间群为C2/c,a=3.4214(4),b=1.1581(2),c=1.7932(5)nm,β=119.76(1)°,V=6.168nm3,Mr=1427.43,Z=4,Dc=1.54g/cm3,μ=12.48cm-1,F(000)=2860,最后偏离因子R=0.066. |
| 关键词: Schiff碱配合物 晶体结构 |
| 基金项目: 山东大学晶体材料国家重点实验室资助 |
| Abstract: The title complex of trinuclecadmium complex Cd3[CH3O(O)C6H3CH=NNHC(S)NH2]4·[CH3COO]2·1/2[CH3S(O)CH3]·2H2O was synthesized and its structure was determined by single crystal X-ray diffraction method. The complex crytallizes in the monocline. space group is C2/c, with cell parameters: a=3.4214(4), b=1. 1581(2), c=1.7932(5)nm. β=119.76(l)°,V=6. 168nm3, Mr=1427.45, Z=4, Dc=1.54g / cm3,μ=12.48cm-1, F(000)=2860, final R=0.066 for 2387 unique reflections [I>3(δ)]. |
| Keywords: Schiffbase complex crystal structure |
| 投稿时间：1994-03-18 |
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| 崔学桂,胡清萍,杨立群.含硫、氮Schiff碱配合物—二水二分之一二甲基亚砜醋酸四邻香草醛缩胺基硫脲合镉(Ⅱ)的合成及晶体结构[J].无机化学学报,1995,11(1):46-51. |
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