YbCl3-CaCl2-MgCl2三元体系液相限的研究
AN INVESTIGATION ON THE LIQUIDUS OF TERNARY SYSTEM YbCl3-CaCl2-MgCl2
作者单位
彭绍琴 南昌大学化学系 
郑朝贵 北京大学化学系, 北京100871 
摘要: 借助于DTA测定了YbCl3-CaCl2-MgCl2三元体系液相限.发现本体系有对应于YbCl3、CaCl2、MgCl2和不稳定化合物X的四个液相面,五条二次结晶线,一个三元低共熔点E(38.0wt%YbCl3,31.0wt%CaCl2,31.0wt%MgCl2;556℃)和三元转熔点P'(45.5wt%YbCl3,28.0wt%CaCl2,26.5wt%MgCl2;600℃).
关键词: 相图  YbCl3-CaCl2-MgCl2  三元体系  YbCl3
基金项目: 国家自然科学基金
Abstract: The liquidus of ternary system YbCl3-CaCl2-MgCl2 has been investigated by means of DTA. It was found that there arc four surfaces coryesponding to the primary crystallization of YbCl3, CaCl2, MgCl2 and unstable compound X respectively, and five univariant curves to the secondary ctystallization. The temperature of the ternary cutectic, composed of 38.0wt%YbCl3, 31.0wt% CaCl2, 31.0wt% MgCl2, was determined to be 556℃. The temperature of the ternary peritecti-like, composed of 45.5wt% YbCl3, 28.0wt% CaCl2, 26.5wt% MgCl2, was observed to be 600℃.
Keywords: phase diagram  YbCl3-CaCl2-MgCl2  ternary system  YbCl3
投稿时间:1994-05-25 
摘要点击次数:  1950
全文下载次数:  2033
彭绍琴,郑朝贵.YbCl3-CaCl2-MgCl2三元体系液相限的研究[J].无机化学学报,1995,11(2):208-211.
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