| 冠醚配合物的研究XV.若干席夫碱及仲胺型双冠醚和碱金属离子的配位反应 |
| STUDIES ON CROWN ETHERS COMPOUNDS X V.COORDINATION REACTION OF BIS-CROWN ETHERS WITH ALKALINE METAL IONS IN DMF |
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| 摘要: 本文运用微量电导滴定及计算机拟合技术,研究了若干席夫碱及仲胺型双冠醚和减金属离子的配位反应,测定了配合物的组成及稳定常数,并对实验结果进行了讨论. |
| 关键词: 双冠醚 碱金属离子 电导滴定 稳定常数 |
| 基金项目: |
| Abstract: The reaction of schiff base type and secondary amine type his-crown ethers compounds with alkaline metal ions were determined by microconductomctric titration and computer fitting. The stability constants of coordination compounds were obtained. The results shown that the his-crown ethers formed 1:1 complexes with metal ions in DMF and the stability of complexes are relative to the length of carbon chain between two crown units in his-crown ether molcculars. |
| Keywords: bis-crown ether alkaline metalion conductometric titration stability constant |
| 投稿时间：1994-10-14 |
| 摘要点击次数: 1365 |
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| 耿金龙,王志林,曹建国,巫士华,朱春生,罗勤慧.冠醚配合物的研究XV.若干席夫碱及仲胺型双冠醚和碱金属离子的配位反应[J].无机化学学报,1995,11(3):281-284. |
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