希土水杨酸与8─羟基喹啉三元配合物研究
STUDIES ON TERNARY COMPLEXES OF RARE EARTH WITH SALICYLIC ACID AND 8-HYDROXYQUINOLINE
作者单位
王则民 上海师范大学化学系, 上海200234 
曹锦荣 上海师范大学化学系, 上海200234 
周德兴 上海师范大学化学系, 上海200234
上海师大生化公司 
杨海峰 上海师范大学化学系, 上海200234
上海师大生化公司 
摘要: 合成了六种希土(RE)-水杨酸(H2sal)-8-羟基喹啉(Hhq)三元固体配合物,其通式为RE(Hsal)2·hq(RE=Y,La,Nd,Sm,Ho,Er).通过元素分析、摩尔电导、IR、Far-IR、UV-Vis、TG-DTA分析,研究了配合物的组成、性质和成键特性.通过抑菌试验表明配合物对于霉菌具有抑真菌能力.
关键词: 希土  水杨酸  8-羟基喹啉  三元配合物  抑真菌
基金项目: 
Abstract: Six new solid complexes of rare earth with salicylic acid(H2sal)and 8-hydroxyquinoline(Hhq)were prepared. These complexes all have the composition of RE(Hsal)2·hq(RE=Y,La,Nd,Sm,Ho,Er;Hsal=C7H5O3;hq=C9H6NO). The compositions.propertics and bonding specificity between RE3+ and ligands have been confirmed by clemental analysis,molar conductancc,IR,Far-IR,UV,Vis and TG-DTA mcasurcmcnts.Results from fungistatic testing indieated that these complexes all have fungistatic ability on molds.
Keywords: rare earth  salicylic acid  8-hydroxyquinollne  ternary complex  fungistasis
投稿时间:1994-11-19 
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王则民,曹锦荣,周德兴,杨海峰.希土水杨酸与8─羟基喹啉三元配合物研究[J].无机化学学报,1995,11(3):308-312.
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